I have messed around and around.. Tried multiple emulators that all work stand alone to no avail. When viewing the log can see the problem is:
21:08:12.2 5/20/2013: Running: cmd.exe /c S: snes9x.exe -fullscreen "S:\_Good Stuff\HTPC\emulators\emu\Nintendo_SNES\roms\Super Mario Kart.zip"
It is neglecting the path to snes9x. It does this for all the emulators. I've tried searching the forums to no avail. What have I done wrong?